VALORIZATION OF GLYCEROL INTO BIOFUEL ADDITIVES HETEROPOLYACIDS SUPPORTED IN ACID SOLIDS
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Centro para a Valorização de Resíduos
Abstract
Tungstosilicic acid (SiW) immobilized in silica with different amount has got high catalytic activity for the acetalisation of glycerol with butanal. The SiW2-S catalysts showed the highest catalytic activity.
All catalysts showed high values of selectivity to five-member ring acetal (about 80-83%).
PW2-S showed good catalytic stability. After the forth use, it was observed that the catalytic activity decreased about 6 % of its initial value.
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F.I. Santos, J. Farinha, J.E. Castanheiro, Valorization of glycerol into biofuel additives over heteropolyacids supported in acid solids, WASTES: SOLUTIONS, TREATMENTS AND OPPORTUNITIES-3RD INTERNATIONAL CONFERENCE, Viana do Castelo, Portugal, Setembro, 14-16, 2015.