Synthesis and electrochemical studies of organometallic cobalt(III) complexes with substituted benzonitrile chromophores: NMR spectroscopic data as a probe on the second-order non-linear optical properties

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dc.contributor.authorMendes, Paulo J.
dc.date.accessioned2012-10-10T16:31:27Z
dc.date.available2012-10-10T16:31:27Z
dc.date.issued2005
dc.description.abstractThe family of organometallic Co(III) benzonitrile derivatives of general formula [CoCp(dppe)(p-NCR)][PF6]2 (R=C6H4NMe2, C6H4NH2, C6H4OMe, C6H4C6H5, C6H5, C6H4C6H4NO2 and C6H4NO2) have been synthesized. Spectroscopic and electrochemical data were analyzed in order to evaluate the extent of electronic coupling between the organometallic fragment and the nitrile ligands. An attempt of correlation between NMR spectroscopic data and the second-order non-linear optical properties is presented, based on this work and available published data for related η5-monocyclopentadienyliron, ruthenium and nickel complexes.por
dc.identifier.authoremailpjgm@uevora.pt
dc.identifier.citationJournal of Organometallic Chemistry 690 (2005) 4063-4071por
dc.identifier.revistaJournal of Organometallic Chemistry
dc.identifier.scientificarea306por
dc.identifier.sharewithQUI-Publicações-Artigos em Revistas Internacionais com Arbitragem Científicapor
dc.identifier.urihttp://www.sciencedirect.com/science/article/pii/S0022328X0500450X
dc.identifier.urihttp://hdl.handle.net/10174/5323
dc.identifier.volume690
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherElsevierpor
dc.rightsopenAccesspor
dc.subjectCobalt complexespor
dc.subjectBenzonitrile derivativespor
dc.subjectCyclic voltammetrypor
dc.subjectElectronic couplingpor
dc.subjectNon-linear opticspor
dc.titleSynthesis and electrochemical studies of organometallic cobalt(III) complexes with substituted benzonitrile chromophores: NMR spectroscopic data as a probe on the second-order non-linear optical propertiespor
dc.typearticlepor
degois.publication.firstPage4063por
degois.publication.lastPage4071por
degois.publication.titleJournal of Organometallic Chemistrypor
degois.publication.volume690por

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