The benzilic ester rearrangement: synthesis of labelled compounds and theoretical studies

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dc.contributor.authorMarques, Carolina S.
dc.contributor.authorRamalho, J. P. Prates
dc.contributor.authorBurke, Anthony J.
dc.date.accessioned2012-11-21T19:11:42Z
dc.date.available2012-11-21T19:11:42Z
dc.date.issued2009
dc.date.updated2012-11-16T14:44:55Z
dc.description.abstract1,3-Diphenyl-2(13C)-hydroxy-3-methoxypropan-1-one was synthesised and used to probe the mechanism of a benzilic ester rearrangement (BER). Computational studies suggest that the preferred site of attack of the nucleophile in this benzilic ester rearrangement is on C-14. On the basis of these results a new reaction mechanism is proposed.por
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dc.identifier.citationMarques, Carolina S.; Ramalho, J. P. Prates; Burke, Anthony J.The benzilic ester rearrangement: synthesis of labelled compounds and theoretical studies, Journal of Physical Organic Chemistry, 22, 8, 735-739, 2009.por
dc.identifier.doi10.1002/poc.1509
dc.identifier.scientificarea307por
dc.identifier.urihttp://hdl.handle.net/10174/5893
dc.language.isoporpor
dc.peerreviewedyespor
dc.rightsrestrictedAccesspor
dc.subjectbenzilic ester rearrangementpor
dc.subjectlabelling studiespor
dc.subjectfukui functionpor
dc.subjectdensity functional theorypor
dc.titleThe benzilic ester rearrangement: synthesis of labelled compounds and theoretical studiespor
dc.typearticlepor

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